Functionalization of 6-Nitrobenzo[1,3]dioxole with Carbonyl Compounds via TDAE methodology
نویسندگان
چکیده
منابع مشابه
Functionalization of 6-nitrobenzo[1,3]dioxole with carbonyl compounds via TDAE methodology.
We report herein the synthesis of substituted 2-(6-nitrobenzo[1,3]dioxol-5-yl)-1- aryl ethanols and 2-(6-nitrobenzo[1,3]dioxol-5-yl)-propionic acid ethyl esters from the reaction of 5-chloromethyl-6-nitrobenzo[1,3]dioxole with various aromatic carbonyl and alpha- carbonyl ester derivatives using the tetrakis(dimethylamino)ethylene (TDAE) methodology.
متن کاملRecent trends in Pd-catalyzed remote functionalization of carbonyl compounds.
Recent advances in the palladium-catalyzed remote functionalization of carbonyl derivatives are highlighted in this review. The structure of the article is based on the three strategies that have emerged in recent years as the most viable tactics to construct C(sp(3))-C, C(sp(3))-N or C(sp(3))-O bonds at a distance of at least three carbon atoms from the carbonyl functionality. The specific asp...
متن کاملSOLID STATE DESEMICARBAZONATION WITH HEXAMETHYLENETETRAMINE-BROMINE: REGENERATION OF CARBONYL COMPOUNDS USING MICROWAVES
Hexamethylenetetramine-bromine on wet alumina rapidly regenerates carbonyl compounds from their corresponding semicarbazone using microwave under solventless system.
متن کاملSynthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR].
The reaction between a transition metal carbonyl compound, L(n)MCO, and Li[Me(3)SiNR] yields the corresponding isocyanide derivative, L(n)MCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Molecules
سال: 2005
ISSN: 1420-3049
DOI: 10.3390/10030545